BPSC TRE 1 PYQ Quiz – Higher Secondary Teacher Exam Subject Chemistry

BPSC TRE Previous Question Paper Quiz

विद्यालय अध्यापक परीक्षा के पूछे गए प्रश्न

For Class (1-5), (6-8), (9-10), (11-12)


 

Results

#1. Which of the following will have the most negative electron gain enthalpy?

Explanation: Chlorine has the most negative electron gain enthalpy among halogens due to optimal atomic size for electron acceptance.

#2. Which of the following data is expressed in scientific notation?

Explanation: Proper scientific notation requires coefficient between 1 and 10.

#3. N atom has 3 unpaired electrons because of

Explanation: Hund’s rule states electrons occupy degenerate orbitals singly before pairing up.

#4. Which molecule contains both ionic and covalent bonds?

Explanation: NH₄Cl has covalent bonds in NH₄⁺ and ionic bond between NH₄⁺ and Cl⁻.

#5. The effective nuclear charge for Na (11) is

Explanation: Effective nuclear charge = atomic number – inner electrons = 11 – 10 = +1.




#6. Arrange the following elements in the increasing order of metallic character : Si, Be, Mg, Na

Explanation: Metallic character increases down the group and decreases across period.

#7. Using s, p, d, f notations, find the orbital with quantum numbers n = 2, l = 1.

Explanation: For n=2, l=1 corresponds to p orbital, so 2p.

#8. Which of the following ions has the smallest ionic radius?

Explanation: Zn²⁺ has the smallest ionic radius due to d-block contraction. All are isoelectronic (18 electrons), but Zn²⁺ has higher effective nuclear charge.

#9. Po belongs to which period and group in the periodic table?

Explanation: Polonium (Po) is in period 6, group 16 (oxygen group).

#10. A 2·5 L flask contains 0·25 mol each of sulphur dioxide and nitrogen gas at 27 °C. The partial pressure of SO₂ is

Explanation: Using PV = nRT, P = nRT/V = (0.25 × 8.314 × 300)/0.0025 = 2.49 × 10⁵ Pa.




#11. Which of the following is the correct formula for kinetic energy based on dimensional arguments?

Explanation: Dimensions of KE are ML²T⁻², which matches ½mv².

#12. The geometrical shape of PCl₅ molecules is

Explanation: PCl₅ has sp³d hybridization with 5 bond pairs.

#13. Which of the following molecules has T-shaped geometry?

Explanation: ClF₃ has 3 bond pairs and 2 lone pairs → T-shaped.

#14. CO₂ is isostructural with which of the following?

Explanation: Both CO₂ and C₂H₂ are linear molecules.

#15. Which of the following is molecular solid?

Explanation: Methane (CH₄) is a molecular solid with weak van der Waals forces.




#16. Which of the following molecules has zero dipole moment?

Explanation: CO₂ is linear and symmetrical, dipole moments cancel.

#17. How many π bonds are present in HC≡CCH=CHCH₃?

Explanation: Triple bond (2π) + double bond (1π) = 3π bonds.

#18. Repulsion is maximum in

Explanation: lp-lp > lp-bp > bp-bp in VSEPR theory.

#19. Which of the following molecules shows metamerism?

Explanation: Ethers with formula C₄H₁₀O show metamerism.

#20. When sodium and chlorine react, then the energy

Explanation: NaCl formation is exothermic with ionic bonding.




#22. A gas can be liquefied by pressure only if its temperature is

Explanation: Liquefaction by pressure requires temperature below critical temperature.

#23. Which of the following reactions involves homogeneous equilibrium?

Explanation: All reactants and products are gases → homogeneous equilibrium.

#24. In 2NH₃ → N₂ + 3H₂, the order of the reaction is

Explanation: Decomposition of NH₃ on tungsten surface is zero order.

#25. Which of the following statements is correct?

Explanation: Both A and B are correct; K is independent of initial concentrations.




#26. Which of the following equations represents Bragg’s law?

Explanation: This is the standard Bragg’s equation for X-ray diffraction.

#27. Write the conjugate acids for the following Brönsted bases : NH²⁻, NH₃, HCOO⁻

Explanation: Correct conjugate acids are NH₃ (for NH²⁻), NH₄⁺ (for NH₃), HCOOH (for HCOO⁻).

#28. Determine the oxidation numbers of the active elements in the following compounds : KMnO₄, K₂Cr₂O₇, KClO₄

Explanation: Mn in KMnO₄ = +7, Cr in K₂Cr₂O₇ = +6, Cl in KClO₄ = +7.

#29. Which of the following is the correct equation?

Explanation: This is Gibbs free energy equation.

 

#30. Which of the following is not the correct statement?

Explanation: Proton (H⁺) is a Lewis acid, not base.




#31. In the evaporation of water, the entropy

Explanation: Water molecules become more disordered during evaporation.

#32. The degree of ionization of a 0·1 M bromoacetic acid solution is 0·132. The pH of the solution is

Explanation: [H⁺] = Cα = 0.1 × 0.132 = 0.0132; pH = -log(0.0132) ≈ 1.88.

#33. Which compound is insoluble in water?

Explanation: Barium sulfate is insoluble (common solubility rule).

#34. Choose the correct statement.

Explanation: All three statements A, B, and C are correct.

#35. Which indicator will be suitable for the titration of HCOOH and NaOH?

Explanation: Weak acid-strong base titration uses phenolphthalein (pH 8-10).




#36. Choose the correct statement.

Explanation: Both B and C are correct statements.

#37. The order of correct acidic strengths of halogen acids is

Explanation: Acid strength: HI > HBr > HCl > HF due to bond dissociation energy.

#38. Which of the following has the lowest boiling point?

Explanation: H₂O has H-bonding (highest bp), H₂Se > H₂S due to larger size.

#39. In ClF₃, the nature of hybridization is

Explanation: ClF₃ has 3 bond pairs + 2 lone pairs → sp³d hybridization.




#41. Cr has electronic configuration

Explanation: Chromium shows exceptional configuration due to extra stability of half-filled d orbitals.

 

#42. The concentration of ore is carried out by which of the following methods?

Explanation: Both magnetic separation and froth flotation are ore concentration methods; roasting is a chemical process.

#43. Which of the following methods is used for the purification of zirconium?

Explanation: Zirconium is purified by Van Arkel method (iodide process).

#44. The highest oxidation state of any transition metal is

Explanation: Osmium and ruthenium show +8 oxidation state (e.g., OsO₄, RuO₄).

#45. Cell reaction will be spontaneous if

Explanation: Spontaneity requires ΔG < 0 (negative).




#46. Which of the following is the electron-precise hydride?

Explanation: CH₄ has exact number of electrons for covalent bonds (8 electrons around C).

#47. The atomic number of Cu is 29. Its EAN in [Cu(NH₃)₄]²⁺ is

Explanation: EAN = Atomic number – oxidation state + 2 × coordination number = 29 – 2 + (2×4) = 35.

#48. Which of the following alkali metals forms superoxide?

Explanation: Both K and Rb form superoxides (KO₂, RbO₂).

#49. Which of the following alkaline earth metals imparts colour to the flame?

Explanation: Both Ca (brick red) and Sr (crimson red) impart color to flame.

#50. The IUPAC name of K₃[Fe(CN)₆] is

Explanation: This is the systematic IUPAC name; note options A and C appear identical in text.




#51. Setting of cement gets slower by adding

Explanation: Gypsum (CaSO₄·2H₂O) retards setting of cement.

#52. Which complex has square planar structure?

Explanation: [Ni(CN)₄]²⁻ is square planar due to dsp² hybridization.

#53. Which of the following compounds is used as a purgative in medicine?

Explanation: MgSO₄ (Epsom salt) is used as a laxative/purgative.

#54. The chemical formula of sodium nitroprusside is

Explanation: Sodium nitroprusside is Na₂[Fe(CN)₅NO]·2H₂O.

#55. Which of the following is known as ‘inorganic benzene’?

Explanation: B₃N₃H₆ has structure and properties similar to benzene.




#56. Homolytic fission of the bond will form

Explanation: Homolytic cleavage gives free radicals with unpaired electrons.

#57. Which of the following boron compounds is used as a reducing agent in organic synthesis?

Explanation: Lithium borohydride is used as reducing agent for carbonyl compounds.

#58. Select the electrophilic reagent out of the following.

Explanation: Both Br⁺ (electrophile) and AlCl₃ (Lewis acid/electrophile) are electrophilic.

#60. The rotation of plane-polarized light is measured by

Explanation: Polarimeter measures optical rotation.




#61. Pure nitrogen can be obtained by which of the following reactions?

Explanation: All three reactions produce pure nitrogen gas.

#62. The alkane obtained by the electrolysis of potassium acetate is

Explanation: Kolbe electrolysis of potassium acetate gives ethane (C₂H₆).

#63. Which of the following oxides of nitrogen is used as an anaesthetic?

Explanation: Nitrous oxide (N₂O) is “laughing gas” used as anaesthetic.

#64. The hydrocarbon formed by the action of sodium on ethyl iodide is

Explanation: Wurtz reaction: 2C₂H₅I + 2Na → C₄H₁₀ + 2NaI.

#65. In which C—C bond of CH₃CH₂CH₂Br, the inductive effect is expected to be the least?

Explanation: Inductive effect decreases with distance from Br; C₂—C₃ farthest.




#66. When acetylene is passed through dilute H₂SO₄ in the presence of HgSO₄, the compound obtained is

Explanation: Hydration of acetylene gives acetaldehyde (Kucherov reaction).

#67. Identify the following transformation according to the reaction type : H₂C=CH—CH₂CH₃ → H₃CCH=CHCH₃

Explanation: Double bond migration is isomerization.

#68. Which of the following compounds shows cis-trans isomerism?

Explanation: Has two different groups on each carbon of double bond → cis-trans possible.

#69. Nitric acid is reduced to nitrogen dioxide in which of the following reactions?

Explanation: Both reactions A and B produce NO₂ from HNO₃.

#70. The synthetic method developed for the manufacture of petrol is

Explanation: Both Fischer-Tropsch and Bergius processes produce synthetic petrol.




#71. Natural rubber is a polymer of

Explanation: Natural rubber is cis-polyisoprene.

#72. Which of the following is non-aromatic based on Hückel’s rule?

Explanation: All are aromatic (have 4n+2 π electrons in cyclic conjugated system).

#73. Conformations can be represented by

Explanation: Both sawhorse and Newman projections show conformations.

#74. Which of the following reduces Tollens’ reagent?

Explanation: Glucose is reducing sugar that gives silver mirror with Tollens’ reagent.

#75. Which of the following pesticides is out of use?

Explanation: DDT banned in many countries due to environmental persistence.




#76. Arrange the following halides in order of increasing S_N2 reactivity : CH₃Cl, CH₃CH₂Cl, (CH₃)₂CHCl

Explanation: S_N2 reactivity decreases with increasing steric hindrance.

#77. Lassaigne’s test is not used for the detection of

Explanation: Lassaigne’s test detects N, S, halogens; phosphorus requires separate test.

#78. Which of the following is used in industry as a solvent for fats, waxes, resins and rubbers?

Explanation: Both CH₂Cl₂ and CHCl₃ are used as solvents for these materials.

#79. Which of the following isomers has a high melting point?

Explanation: Para isomer has symmetrical structure → higher melting point.

#80. Which of the following compounds is most acidic in character?

Explanation: Acetylene (ethyne) has acidic hydrogen due to sp hybridization.




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